Code of Federal Regulations (alpha)

CFR /  Title 40  /  Part 419  /  Sec. 419.42 Effluent limitations guidelines representing the degreepracticable control

technology currently available (BPT).

(a) Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart must achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT): ------------------------------------------------------------------------

BPT effluent limitations

---------------------------

Average of

daily values

Pollutant or pollutant property Maximum for for 30

any 1 day consecutive

days shall

not exceed------------------------------------------------------------------------

Metric units (kilograms

per 1,000 m\3\ of

feedstock)

---------------BOD\5\...................................... 50.6 25.8TSS......................................... 35.6 22.7COD \1\..................................... 360.0 187.0Oil and grease.............................. 16.2 8.5Phenolic compounds.......................... 0.38 0.184Ammonia as N................................ 23.4 10.6Sulfide..................................... 0.33 0.150Total chromium.............................. 0.77 0.45Hexavalent chromium......................... 0.068 0.030pH.......................................... (\2\) (\2\)

---------------

English units (pounds per

1,000 bbl of feedstock)

---------------BOD5........................................ 17.9 9.1TSS......................................... 12.5 8.0COD \1\..................................... 127.0 66.0Oil and grease.............................. 5.7 3.0Phenolic compounds.......................... 0.133 0.065Ammonia as N................................ 8.3 3.8Sulfide..................................... 0.118 0.053Total chromium.............................. 0.273 0.160Hexavalent chromium......................... 0.024 0.011pH.......................................... (\2\) (\2\)------------------------------------------------------------------------\1\ See footnote following table in Sec. 419.13(d).\2\ Within the range of 6.0 to 9.0.

(b) The limits set forth in paragraph (a) of this section are to be multiplied by the following factors to calculate the maximum for any one day and maximum average of daily values for thirty consecutive days.

(1) Size factor. ------------------------------------------------------------------------

Size

1,000 bbl of feedstock per stream day factor------------------------------------------------------------------------Less than 49.9.............................................. 0.7150.0 to 74.9................................................ 0.7475.0 to 99.9................................................ 0.81100.0 to 124.9.............................................. 0.88125.0 to 149.9.............................................. 0.97150.0 to 174.9.............................................. 1.05175.0 to 199.9.............................................. 1.14200.0 or greater............................................ 1.19------------------------------------------------------------------------

(2) Process factor. ------------------------------------------------------------------------

Process

Process configuration factor------------------------------------------------------------------------Less than 6.49.............................................. 0.816.5 to 7.49................................................. 0.887.5 to 7.99................................................. 1.008.0 to 8.49................................................. 1.098.5 to 8.99................................................. 1.199.0 to 9.49................................................. 1.299.5 to 9.99................................................. 1.4110.0 to 10.49............................................... 1.5310.5 to 10.99............................................... 1.6711.0 to 11.49............................................... 1.8211.5 to 11.99............................................... 1.9812.0 to 12.49............................................... 2.15

12.5 to 12.99............................................... 2.3413.0 or greater............................................. 2.44------------------------------------------------------------------------

(3) Example of the application of the above factors. Example--Lube refinery 125, 000 bbl per stream day throughput.

Calculation of the Process Configuration------------------------------------------------------------------------

Weighting

Process category Process included factor------------------------------------------------------------------------Crude.......................... Atm crude distillation...... 1

Vacuum, crude distillation..

Desalting...................Cracking and coking............ Fluid cat. cracking......... 6

Vis-breaking................

Thermal cracking............

Moving bed cat. cracking....

Hydrocracking...............

Fluid coking................

Delayed coking..............Lube........................... Further defined in the 13

development document.Asphalt........................ Asphalt production.......... 12

Asphalt oxidation...........

Asphalt emulsifying.........------------------------------------------------------------------------ ----------------------------------------------------------------------------------------------------------------

Capacity Capacity

(1,000 bbl relative Weighting Processing

Process per stream to Factor configuration

day) throughput----------------------------------------------------------------------------------------------------------------Crude:

Atm....................................................... 125.0 1.0 ......... .............

Vacuum.................................................... 60.0 0.48 ......... .............

Desalting................................................. 125.0 1.0 ......... .............

Total.................................................... ............ 2.48 x1 =2.48Cracking-FCC................................................ 41.0 0.328 ......... .............Hydrocracking............................................... 20.0 0.160 ......... .............

Total.................................................... ............ 0.488 x6 =2.93Lubes....................................................... 5.3 0.042 ......... .............

4.0 0.032 ......... .............

4.9 0.039 ......... .............

Total.................................................... ............ 0.113 x13 =1.47Asphalt..................................................... 4.0 0.032 x12 = .38Refinery process configuration.............................. ............ .......... ......... =7.26----------------------------------------------------------------------------------------------------------------Notes:See table Sec. 419.42(b)(2) for process factor. Process factor=0.88.See table Sec. 419.42(b)(1) for size factor for 125,000 bbl per stream day lube refinery. Size factor=0.97.To calculate the limits for each parameter, multiply the limit Sec. 419.42(a) by both the process factor and

size factor. BOD5 limit (maximum for any 1 day)=17.9x0.88x0.97=15.3 lb. per 1,000 bbl of feedstock.

(c) The provisions of Sec. 419.12(c) apply to discharges of process wastewater pollutants attributable to ballast water by a point source subject to the provisions of this subpart.

(d) The quantity and quality of pollutants or pollutant properties controlled by this paragraph, attributable to once-through cooling water, are excluded from the discharge allowed by paragraph (b) of this section. Once-through cooling water may be discharged with a total organic carbon concentration not to exceed 5 mg/l.

(e) Effluent limitations for contaminated runoff. The following effluent limitations constitute the quantity and quality of pollutants or pollutant properties controlled by this paragraph and attributable to contaminated runoff, which may be discharged after the application of the best practicable control technology currently available by a point source subject to this subpart.

(1) If wastewater consists solely of contaminated runoff and is not commingled or treated with process wastewater, it may be discharged if it does not exceed 15 mg/l oil and grease and 110 mg/l total organic carbon (TOC) based upon an analysis of any single grab or composite sample.

(2) If contaminated runoff is commingled or treated with process wastewater, or if wastewater consisting solely of contaminated runoff which exceeds 15 mg/l oil and grease or 110 mg/l TOC is not commingled or treated with any other type of wastewater, the quantity of pollutants discharged shall not exceed the quantity determined by multiplying the flow of contaminated runoff as determined by the permit writer times the concentrations listed in the following table: ------------------------------------------------------------------------

BPT effluent limitations

for contaminated runoff

---------------------------

Average of

Pollutant or pollutant property daily values

Maximum for for 30

any 1 day consecutive

days shall

not exceed------------------------------------------------------------------------

Metric units (kilograms

per 1,000 m\3\ of flow)

---------------BOD5........................................ 48. 26.TSS......................................... 33. 21.COD \1\..................................... 360. 180.Oil and grease.............................. 15. 8.Phenolic compounds (4AAP)................... 0.35 0.17Total chromium.............................. 0.73 0.43Hexavalent chromium......................... 0.062 0.028pH.......................................... (\2\) (\2\)

---------------

English units (pounds per

1,000 gallons of flow)

---------------BOD5........................................ 0.40 0.22TSS......................................... 0.28 0.18COD \1\..................................... 3.0 1.5Oil and grease.............................. 0.13 0.067Phenolic compounds (4AAP)................... 0.0029 0.0014Total chromium.............................. 0.0060 0.0035Hexavalent chromium......................... 0.00052 0.00023pH.......................................... (\2\) (\2\)------------------------------------------------------------------------\1\ In any case in which the applicant can demonstrate that the chloride

ion concentration in the effluent exceeds 1,000 mg/l (1,000 ppm), the

permitting authority may substitute TOC as a parameter in lieu of COD.

A TOC effluent limitation shall be based on effluent data from the

particular refinery which correlates TOC to BOD5. If in the judgment

of the permitting authority, adequate correlation data are not

available, the effluent limitations for TOC shall be established at a

ratio of 2.2 to 1 to the applicable effluent limitations for BOD5.\2\ Within the range of 6.0 to 9.0. [47 FR 46446, Oct. 18, 1982, as amended at 50 FR 28522, 28523, July 12, 1985; 50 FR 32414, Aug. 12, 1985]