(a) This subpart can be implemented and enforced by the U.S. EPA, or a delegated authority such as the applicable State, local, or Tribal agency. If the U.S. EPA Administrator has delegated authority to a State, local, or Tribal agency, then that agency, in addition to the U.S. EPA, has the authority to implement and enforce this subpart. Contact the applicable U.S. EPA Regional Office to find out if implementation and enforcement of this subpart is delegated to a State, local, or Tribal agency.
(b) In delegating implementation and enforcement authority of this subpart to a State, local, or Tribal agency under subpart E of this part, the authorities contained in paragraph (c) of this section are retained by the Administrator of U.S. EPA and cannot be transferred to the State, local, or Tribal agency.
(c) The authorities that cannot be delegated to State, local, or Tribal agencies are as specified in paragraphs (c)(1) through (4) of this section.
(1) Approval of alternatives to the requirements in Sec. Sec. 63.1400 through 63.1401 and 63.1404 through 63.1410. Where these standards reference another subpart, the cited provisions will be delegated according to the delegation provisions of the referenced subpart. Where these standards reference another subpart and modify the requirements, the requirements shall be modified as described in this subpart. Delegation of the modified requirements will also occur according to the delegation provisions of the referenced subpart.
(2) Approval of major alternatives to test methods under Sec. 63.7(e)(2)(ii) and (f), as defined in Sec. 63.90, and as required in this subpart.
(3) Approval of major alternatives to monitoring under Sec. 63.8(f), as defined in Sec. 63.90, and as required in this subpart.
(4) Approval of major alternatives to recordkeeping and reporting under Sec. 63.10(f), as defined in Sec. 63.90, and as required in this subpart.[68 FR 37359, June 23, 2003]
Sec. Table 1 to Subpart OOO of Part 63--Applicability of General
Provisions to Subpart OOO Affected Sources ------------------------------------------------------------------------
Applies to
Reference subpart OOO Explanation------------------------------------------------------------------------63.1(a)(1).................... Yes.............. Sec. 63.1402
specifies
definitions in
addition to or that
supersede
definitions in Sec.
63.2.63.1(a)(2).................... Yes..............63.1(a)(3).................... Yes.............. Sec. 63.1401(i)
identifies those
standards which
overlap with the
requirements of
subpart OOO of this
part and specify how
compliance shall be
achieved.63.1(a)(4).................... Yes.............. Subpart OOO (this
table) specifies the
applicability of
each paragraph in
subpart A of this
part.63.1(a)(5).................... No............... [Reserved].63.1(a)(6).................... Yes..............63.1(a)(7)-63.1(a)(9)......... No............... [Reserved].63.1(a)(10)................... Yes..............
63.1(a)(11)................... Yes..............63.1(a)(12)-63.1(a)(14)....... Yes..............63.1(b)(1).................... No...............63.1(b)(2).................... Yes..............63.1(b)(3).................... No............... Sec. 63.1400(e)
provides
documentation
requirements for
APPUs not considered
affected sources.63.1(c)(1).................... Yes.............. Subpart OOO (this
table) specifies the
applicability of
each paragraph in
subpart A of this
part.63.1(c)(2).................... No............... Area sources are not
subject to this
subpart.63.1(c)(3).................... No............... [Reserved].63.1(c)(4).................... No............... [Reserved].63.1(c)(5).................... Yes.............. Except that affected
sources are not
required to submit
notifications
overridden by this
table.63.1(d)....................... No............... [Reserved].63.1(e)....................... Yes..............63.2.......................... Yes.............. Sec. 63.1402
specifies the
definitions from
subpart A of this
part that apply to
this subpart.63.3.......................... Yes..............63.4(a)(1)-63.4(a)(3)......... Yes..............63.4(a)(4).................... No............... [Reserved].63.4(a)(5).................... Yes..............63.4(b)....................... Yes..............63.4(c)....................... Yes..............63.5(a)(1).................... Yes.............. Except the terms
``source'' and
``stationary
source'' should be
interpreted as
having the same
meaning as
``affected source.''63.5(a)(2).................... Yes..............63.5(b)(1).................... Yes.............. Except Sec.
63.1400(d) specifies
when construction or
reconstruction is
subject to new
source standards.63.5(b)(2).................... No............... [Reserved].63.5(b)(3).................... Yes..............63.5(b)(4).................... Yes.............. Except that the
Initial Notification
and Sec. 63.9(b)
requirements do not
apply.63.5(b)(5).................... Yes..............63.5(b)(6).................... Yes.............. Except that Sec.
63.1400(d) specifies
when construction or
reconstruction is
subject to new
source standards.63.5(c)....................... No............... [Reserved].63.5(d)(1)(i)................. Yes.............. Except that the
references to the
Initial Notification
and Sec.
63.9(b)(5) do not
apply.63.5(d)(1)(ii)................ Yes.............. Except that Sec.
63.5(d)(1)(ii)(H)
does not apply.63.5(d)(1)(iii)............... No............... Sec. 63.1417(e)
specifies
Notification of
Compliance Status
requirements.63.5(d)(2).................... No...............63.5(d)(3).................... Yes.............. Except Sec.
63.5(d)(3)(ii) does
not apply, and
equipment leaks
subject to Sec.
63.1410 are exempt.63.5(d)(4).................... Yes..............63.5(e)....................... Yes..............63.5(f)(1).................... Yes..............63.5(f)(2).................... Yes.............. Except that where
Sec. 63.9(b)(2) is
referred to, the
owner or operator
need not comply.63.6(a)....................... Yes..............63.6(b)(1).................... Yes..............63.6(b)(2).................... Yes..............63.6(b)(3).................... Yes..............63.6(b)(4).................... Yes..............63.6(b)(5).................... Yes..............63.6(b)(6).................... No............... [Reserved].63.6(b)(7).................... No...............63.6(c)(1).................... Yes.............. Except that Sec.
63.1401 specifies
the compliance date.63.6(c)(2).................... No...............63.6(c)(3).................... No............... [Reserved].63.6(c)(4).................... No............... [Reserved].63.6(c)(5).................... Yes..............63.6(d)....................... No............... [Reserved].63.6(e)....................... Yes.............. Except as otherwise
specified in this
table.
63.6(e)(1)(i)................. No............... See Sec.
63.1400(k)(4) for
general duty
requirement.63.6(e)(1)(ii)................ No...............63.6(e)(1)(iii)............... Yes..............63.6(e)(2).................... Yes..............63.6(e)(3).................... No...............63.6(f)(1).................... No...............63.6(f)(2).................... Yes.............. Except Sec.
63.7(c), as referred
to in Sec.
63.6(f)(2)(iii)(D),
does not apply, and
except that Sec.
63.6(f)(2)(ii) does
not apply to
equipment leaks
subject to Sec.
63.1410.63.6(f)(3).................... Yes..............63.6(g)....................... Yes..............63.6(h)....................... No............... This subpart OOO does
not require opacity
and visible emission
standards.63.6(i)(1).................... Yes..............63.6(i)(2).................... Yes..............63.6(i)(3).................... Yes..............63.6(i)(4)(i)(A).............. Yes..............63.6(i)(4)(i)(B).............. No............... Dates are specified
in Sec. Sec.
63.1401(e) and
63.1417(d)(1).63.6(i)(4)(ii)................ No...............63.6(i)(5)-(14)............... Yes..............63.6(i)(15)................... No............... [Reserved].63.6(i)(16)................... Yes..............63.6(j)....................... Yes..............63.7(a)(1).................... Yes..............63.7(a)(2).................... No............... Sec. 63.1417(e)
specifies the
submittal dates of
performance test
results for all
emission points
except equipment
leaks; for equipment
leaks, compliance
demonstration
results are reported
in the Periodic
Reports.63.7(a)(3).................... Yes..............63.7(b)....................... No............... Sec. 63.1417
specifies
notification
requirements.63.7(c)....................... No...............63.7(d)....................... Yes..............63.7(e)(1).................... No............... See Sec.
63.1413(a)(2).63.7(e)(2).................... Yes..............63.7(e)(3).................... No............... Subpart OOO specifies
requirements.63.7(e)(4).................... Yes..............63.7(f)....................... Yes.............. Except that if a site
specific test plan
is not required, the
notification
deadline in Sec.
63.7(f)(2)(i) shall
be 60 days prior to
the performance
test, and in Sec.
63.7(f)(3), approval
or disapproval of
the alternative test
method shall not be
tied to the site
specific test plan.63.7(g)....................... Yes.............. Except that the
requirements in Sec.
63.1417(e) shall
apply instead of the
references to the
Notification of
Compliance Status
report in Sec.
63.9(h). In
addition, equipment
leaks subject to
Sec. 63.1410 are
not required to
conduct performance
tests.63.7(h)....................... Yes.............. Except Sec.
63.7(h)(4)(ii) may
not be applicable,
if the site-specific
test plan in Sec.
63.7(c)(2) is not
required.63.8(a)(1).................... Yes..............63.8(a)(2).................... No...............63.8(a)(3).................... No............... [Reserved].63.8(a)(4).................... Yes..............63.8(b)(1).................... Yes..............63.8(b)(2).................... No............... Subpart OOO specifies
locations to conduct
monitoring.63.8(b)(3).................... Yes..............63.8(c)(1).................... Yes..............63.8(c)(1)(i)................. No...............63.8(c)(1)(ii)................ No...............63.8(c)(1)(iii)............... No...............63.8(c)(2).................... Yes..............63.8(c)(3).................... Yes..............
63.8(c)(4).................... No............... Sec. 63.1415
specifies monitoring
frequency; not
applicable to
equipment leaks
because Sec.
63.1410 does not
require continuous
monitoring systems.63.8(c)(5)-63.8(c)(8)......... No...............63.8(d)....................... No...............63.8(e)....................... No...............63.8(f)(1)-63.8(f)(3)......... Yes..............63.8(f)(4)(i)................. No............... Timeframe for
submitting request
is specified in Sec.
63.1417 (j) or
(k); not applicable
to equipment leaks
because Sec.
63.1410 (through
reference to 40 CFR
part 63, subpart UU)
specifies acceptable
alternative methods.63.8(f)(4)(ii)................ No............... Contents of request
are specified in
Sec. 63.1417(j) or
(k).63.8(f)(4)(iii)............... No...............63.8(f)(5)(i)................. Yes..............63.8(f)(5)(ii)................ No...............63.8(f)(5)(iii)............... Yes..............63.8(f)(6).................... No............... Subpart OOO does not
require continuous
emission monitors.63.8(g)....................... No............... Data reduction
procedures specified
in Sec. 63.1416(a)
and (h); not
applicable to
equipment leaks.63.9(a)....................... Yes..............63.9(b)....................... No............... Subpart OOO does not
require an initial
notification.63.9(c)....................... Yes..............63.9(d)....................... Yes..............63.9(e)....................... No............... Sec. 63.1417
specifies
notification
deadlines.63.9(f)....................... No............... Subpart OOO does not
require opacity and
visible emission
standards.63.9(g)....................... No...............63.9(h)....................... No............... Sec. 63.1417(e)
specifies
Notification of
Compliance Status
requirements.63.9(i)....................... Yes..............63.9(j)....................... No...............63.10(a)...................... Yes..............63.10(b)(1)................... No............... Sec. 63.1416(a)
specifies record
retention
requirements.63.10(b)(2)................... No............... Subpart OOO specifies
recordkeeping
requirements.63.10(b)(3)................... No............... Sec. 63.1400(e)
requires
documentation of
sources that are not
affected sources.63.10(c)...................... No............... Sec. 63.1416
specifies
recordkeeping
requirements.63.10(d)(1)................... Yes..............63.10(d)(2)................... No............... Sec. 63.1417
specifies
performance test
reporting
requirements; not
applicable to
equipment leaks.63.10(d)(3)................... No............... Subpart OOO does not
require opacity and
visible emission
standards.63.10(d)(4)................... Yes..............63.10(d)(5)................... No............... See Sec. 63.1417(g)
for malfunction
reporting
requirements.63.10(e)...................... No............... Sec. 63.1417
specifies reporting
requirements.63.10(f)...................... Yes..............63.11......................... Yes.............. Except that instead
of Sec. 63.11(b),
Sec. 63.1413(g)
shall apply.63.12......................... Yes..............63.13-63.15................... Yes..............------------------------------------------------------------------------ [65 FR 3290, Jan. 20, 2000, as amended at 71 FR 20461, Apr. 20, 2006; 79 FR 60934, Oct. 8, 2014]
Sec. Table 2 to Subpart OOO of Part 63--Known Organic Hazardous Air
Pollutants (HAP) From the Manufacture of Amino/Phenolic Resins ----------------------------------------------------------------------------------------------------------------
Organic HAP subject to cooling tower monitoring
requirements in Sec. 63.1409 (Yes/No)
Organic HAP CAS Number ------------------------------------------------
Column A Column B----------------------------------------------------------------------------------------------------------------Acrylamide.......................... 79-06-1.................. No..................... NoAniline............................. 62-53-3.................. Yes.................... NoBiphenyl............................ 92-52-4.................. Yes.................... YesCresol and cresylic acid (mixed).... 1319-77-3................ Yes.................... NoCresol and cresylic acid (m-)....... 108-39-4................. Yes.................... NoCresol and cresylic acid (o-)....... 95-48-7.................. Yes.................... NoCresol and cresylic acid (p-)....... 106-44-5................. Yes.................... NoDiethanolamine...................... 111-42-2................. No..................... NoDimethylformamide................... 68-12-2.................. No..................... NoEthylbenzene........................ 100-41-4................. Yes.................... YesEthylene glycol..................... 107-21-1................. No..................... NoFormaldehyde........................ 50-00-0.................. Yes.................... NoGlycol ethers....................... 0........................ No..................... NoMethanol............................ 67-56-1.................. Yes.................... YesMethyl ethyl ketone................. 78-93-3.................. Yes.................... YesMethyl isobutyl ketone.............. 108-10-1................. Yes.................... YesNaphthalene......................... 91-20-3.................. Yes.................... YesPhenol.............................. 108-95-2................. Yes.................... NoStyrene............................. 100-42-5................. Yes.................... YesToluene............................. 108-88-3................. No..................... YesXylenes (NOS)....................... 1330-20-7................ Yes.................... YesXylene (m-)......................... 108-38-3................. Yes.................... YesXylene (o-)......................... 95-47-6.................. Yes.................... YesXylene (p-)......................... 106-42-3................. Yes.................... Yes----------------------------------------------------------------------------------------------------------------CAS No. = Chemical Abstract Registry Number.
Sec. Table 3 to Subpart OOO of Part 63--Batch Process Vent Monitoring
Requirements ------------------------------------------------------------------------
Frequency/
Control device Parameters to be recordkeeping
monitored requirements------------------------------------------------------------------------Scrubber \a\................ pH of scrubber Continuous records
effluent, and. as specified in
Sec.
63.1416(d).\b\
Scrubber liquid and Continuous records
gas flow rates. as specified in
Sec.
63.1416(d).\b\Absorber \a\................ Exit temperature of Continuous records
the absorbing as specified in
liquid, and. Sec.
63.1416(d).\b\
Exit specific Continuous records
gravity for the as specified in
absorbing liquid. Sec.
63.1416(d).\b\Condenser \a\............... Exit (product side) Continuous records
temperature. as specified in
Sec. 63.1416(d).
\a\Carbon adsorber \a\......... Total regeneration Record the total
steam flow or regeneration steam
nitrogen flow, or flow or nitrogen
pressure (gauge or flow, or pressure
absolute) during for each carbon bed
carbon bed regeneration cycle.
regeneration
cycle(s), and.
Temperature of the Record the
carbon bed after temperature of the
regeneration and carbon bed after
within 15 minutes each regeneration
of completing any and within 15
cooling cycle(s). minutes of
completing any
cooling cycle(s).Thermal incinerator......... Firebox temperature Continuous records
\c\. as specified in
Sec.
63.1416(d).\b\Catalytic incinerator....... Temperature upstream Continuous records
and downstream of as specified in
the catalyst bed. Sec.
63.1416(d).\b\Boiler or process heater Firebox temperature Continuous records
with a design heat input \c\. as specified in
capacity less than 44 Sec.
megawatts and where the 63.1416(d).\b\
batch process vents or
aggregate batch vent
streams are not introduced
with or used as the primary
fuel.Flare....................... Presence of a flame Hourly records of
at the pilot light. whether the monitor
was continuously
operating during
batch emission
episodes, or
portions thereof,
selected for
control and whether
a flame was
continuously
present at the
pilot light during
said periods.
All control devices......... Diversion to the Hourly records of
atmosphere from the whether the flow
control device or. indicator was
operating during
batch emission
episodes, or
portions thereof,
selected for
control and whether
a diversion was
detected at any
time during said
periods as
specified in Sec.
63.1416(d).
Monthly inspections Records that monthly
of sealed valves. inspections were
performed as
specified in Sec.
63.1416(d).Scrubber, absorber, Concentration level Continuous records
condenser, and carbon or reading as specified in
adsorber (as an alternative indicated by an Sec.
to the requirements organic monitoring 63.1416(d).\b\
previously presented in device at the
this table). outlet of the
control device.------------------------------------------------------------------------\a\ Alternatively, these devices may comply with the organic monitoring
device provisions listed at the end of this table.\b\ ``Continuous records'' is defined in Sec. 63.111.\c\ Monitor may be installed in the firebox or in the ductwork
immediately downstream of the firebox before any substantial heat
exchange is encountered.
Sec. Table 4 to Subpart OOO of Part 63--Operating Parameter Levels ------------------------------------------------------------------------
Established
Device Parameters to be operating
monitored parameter(s)------------------------------------------------------------------------Scrubber.................... pH of scrubber Minimum pH; and
effluent; and minimum liquid/gas
scrubber liquid and ratio
gas flow rates.Absorber.................... Exit temperature of Maximum temperature;
the absorbing and maximum
liquid; and exit specific gravity
specific gravity of
the absorbing
liquid.Condenser................... Exit temperature.... Maximum temperatureCarbon absorber............. Total regeneration Maximum flow or
steam or nitrogen pressure; and
flow, or pressure maximum temperature
(gauge or absolute)
\a\ during carbon
bed regeneration
cycle; and
temperature of the
carbon bed after
regeneration (and
within 15 minutes
of completing any
cooling cycle(s)).Thermal incinerator......... Firebox temperature. Minimum temperatureCatalytic incinerator....... Temperature upstream Minimum upstream
and downstream of temperature; and
the catalyst bed. minimum temperature
difference across
the catalyst bedBoiler or process heater.... Firebox temperature. Minimum temperatureOther devices (or as an Organic HAP Maximum organic HAP
alternate to the concentration level concentration or
requirements previously or reading at reading
presented in this table) outlet of device.
\b\.------------------------------------------------------------------------\a\ 25 to 50 mm (absolute) is a common pressure level obtained by
pressure swing absorbers.\b\ Concentration is measured instead of an operating parameter. Sec. Table 5 to Subpart OOO of Part 63--Reports Required by This Subpart ------------------------------------------------------------------------
Description of
Reference report Due date------------------------------------------------------------------------Sec. 63.1400(j) and Refer to Table 1 and Refer to Subpart A
Subpart A of this part. Subpart A of this of this part.
part.63.1417(d).................. Precompliance Report Existing affected
sources--12 months
prior to the
compliance date.
New affected
sources--with
application for
approval of
construction or
reconstruction.63.1417(e).................. Notification of Within 150 days
Compliance Status. after the
compliance date.63.1417(f).................. Periodic Reports.... Semiannually, no
later than 60 days
after the end of
each 6-month
period. See Sec.
63.1417(f)(1) for
the due date for
the first report.63.1417(f)(12).............. Quarterly reports No later than 60
upon request of the days after the end
administrator. of each quarter.63.1417(h)(1)............... Notification of As specified in 40
storage vessel CFR part 63,
inspection. subpart WW.63.1417(h)(2)............... Site-specific test 90 days prior to
plan. planned date of
test.63.1417(h)(3)............... Notification of 30 days prior to
planned performance planned date of
test. test.63.1417(h)(4)............... Notification of As specified in Sec.
change in primary 63.1400 (g)(7) or
product. (g)(8).
63.1417(h)(5)............... Notification of 180 days prior to
added emission the appropriate
points. compliance date.63.1417(h)(6)............... Notification that a Within 60 days of
small control the redesignation
device has been of control device
redesignated as a size.
large control
device.63.1417(h)(7)............... Notification of Within 60 days after
process change. performance test or
applicability
assessment,
whichever is
sooner.63.1417(h)(8)............... Electronic reporting Within 60 days after
completing
performance test.------------------------------------------------------------------------\a\ Note that the APPU remains subject to this subpart until the
notification under Sec. 63.1400(g)(7) is made. [65 FR 3290, Jan. 20, 2000, as amended at 79 FR 60935, Oct. 8, 2014] Sec. Table 6 to Subpart OOO of Part 63--Coefficients for Total Resource
Effectiveness \a\ ------------------------------------------------------------------------
Values of coefficients
Control device basis --------------------------------------
A B C------------------------------------------------------------------------Flare............................ 5.276x10-1 9.98x10-2 2.096x10-3Thermal Incinerator 0 Percent 4.068x10-1 1.71x10-2 8.664x10-3
Recovery........................Thermal Incinerator 70 Percent 6.868x10-1 3.21x10-3 3.546x10-3
Recovery........................------------------------------------------------------------------------\a\ Use according to procedures outlined in this section.MJ/scm=MegaJoules per standard cubic meter.scm/min=Standard cubic meters per minute.
Subpart PPP_National Emission Standards for Hazardous Air Pollutant
Emissions for Polyether Polyols Production
Source: 64 FR 29439, June 1, 1999, unless otherwise noted.