The owner or operator of each affected source or process unit subject to the requirements of this subpart is required to conduct an initial performance test using the test methods and procedures listed in Sec. 63.7 and paragraph (b) of this section, except as provided in paragraph (c)(1) of this section.
(a) The owner or operator of a process unit seeking to comply with a PM emission limit under Sec. 63.862(a)(1)(ii)(A) must use the procedures in paragraphs (a)(1) and (2) of this section:
(1) Determine the overall PM emission limit for the chemical recovery system at the mill using Equation 1 of this section as follows: [GRAPHIC] [TIFF OMITTED] TR05DE03.004 Where: ELPM = overall PM emission limit for all existing process
units in the chemical recovery system at the kraft or soda
pulp mill, kg/Mg (lb/ton) of black liquor solids fired.Cref, RF = reference concentration of 0.10 g/dscm (0.044 gr/
dscf) corrected to 8 percent oxygen for existing kraft or soda
recovery furnaces.QRFtot = sum of the average volumetric gas flow rates
measured during the performance test and corrected to 8
percent oxygen for all existing recovery furnaces in the
chemical recovery system at the kraft or soda pulp mill, dry
standard cubic meters per minute (dscm/min) (dry standard
cubic feet per minute (dscf/min)).Cref,LK = reference concentration of 0.15 g/dscm (0.064 gr/
dscf) corrected to 10 percent oxygen for existing kraft or
soda lime kilns.QLKtot = sum of the average volumetric gas flow rates
measured during the performance test and corrected to 10
percent oxygen for all existing lime kilns in the chemical
recovery system at the kraft or soda pulp mill, dscm/min
(dscf/min).F1 = conversion factor, 1.44 minutes[middot]kilogram/day[middot]gram
(min[middot]kg/d[middot]g) (0.206 minutes[middot]pound/
day[middot]grain (min[middot]b/d[middot]gr)).BLStot = sum of the average black liquor solids firing rates
of all existing recovery furnaces in the chemical recovery
system at the kraft or soda pulp mill measured during the
performance test, megagrams per day (Mg/d) (tons per day (ton/
d)) of black liquor solids fired.ER1ref, SDT = reference emission rate of 0.10 kg/Mg (0.20 lb/
ton) of black liquor solids fired for existing kraft or soda
smelt dissolving tanks.
(2) Establish an emission limit for each kraft or soda recovery furnace, smelt dissolving tank, and lime kiln; and, using these emissions limits, determine the overall PM emission rate for the chemical recovery system at the mill using the procedures in paragraphs (a)(2)(i) through (v) of this section, such that the overall PM emission rate calculated in paragraph (a)(2)(v) of this section is less than or equal to the overall PM emission limit determined in paragraph (a)(1) of this section, as appropriate.
(i) The PM emission rate from each affected recovery furnace must be determined using Equation 2 of this section as follows:[GRAPHIC] [TIFF OMITTED] TR12JA01.002 Where: ERRF = emission rate from each recovery furnace, kg/Mg (lb/
ton) of black liquor solids.F1=conversion factor, 1.44 min[middot]kg/d[middot]g (0.206 min[middot]/
d[middot]gr).CEL, RF = PM emission limit proposed by owner or operator for
the recovery furnace, g/dscm (gr/dscf) corrected to 8 percent
oxygen.QRF = average volumetric gas flow rate from the recovery
furnace measured during the performance test and corrected to
8 percent oxygen, dscm/min (dscf/min).BLS=average black liquor solids firing rate of the recovery furnace
measured during the performance test, Mg/d (ton/d) of black
liquor solids.
(ii) The PM emission rate from each affected smelt dissolving tank must be determined using Equation 3 of this section as follows:[GRAPHIC] [TIFF OMITTED] TR12JA01.003 Where: ERSDT = emission rate from each SDT, kg/Mg (lb/ton) of black
liquor solids fired.F1=conversion factor, 1.44 min[middot]kg/dg (0.206
min[middot]lb/d[middot]gr).CEL, SDT = PM emission limit proposed by owner or operator
for the smelt dissolving tank, g/dscm (gr/dscf).QSDT = average volumetric gas flow rate from the smelt
dissolving tank measured during the performance test, dscm/min
(dscf/min).BLS=average black liquor solids firing rate of the associated recovery
furnace measured during the performance test, Mg/d (ton/d) of
black liquorsolids fired. If more than one SDT is used to
dissolve the smelt from a given recovery furnace, then the
black liquor solids firing rate of the furnace must be
proportioned according to the size of the SDT.
(iii) The PM emission rate from each affected lime kiln must be determined using Equation 4 of this section as follows:[GRAPHIC] [TIFF OMITTED] TR12JA01.004 Where: ERLK = emission rate from each lime kiln, kg/Mg (lb/ton) of
black liquor solids.F1=conversion factor, 1.44 min[middot]kg/d[middot]g (0.206
min[middot]lb/d[middot]gr).CEL,LK = PM emission limit proposed by owner or operator for
the lime kiln, g/dscm (gr/dscf) corrected to 10 percent
oxygen.QLK = average volumetric gas flow rate from the lime kiln
measured during the performance test and corrected to 10
percent oxygen, dscm/min (dscf/min).CaOLK = lime production rate of the lime kiln, measured as
CaO during the performance test, Mg/d (ton/d) of CaO.CaOtot = sum of the average lime production rates for all
existing lime kilns in the chemical recovery system at the
mill measured as CaO during the performance test, Mg/d (ton/
d).BLStot = sum of the average black liquor solids firing rates
of all recovery furnaces in the chemical recovery system at
the mill measured during the performance test, Mg/d (ton/d) of
black liquor solids.
(iv) If more than one similar process unit is operated in the chemical recovery system at the kraft or soda pulp mill, Equation 5 of this section must be used to calculate the overall PM emission rate from all similar process units in the chemical recovery system at the mill and must be used in determining the overall PM emission rate for the chemical recovery system at the mill:[GRAPHIC] [TIFF OMITTED] TR12JA01.005 Where: ERPUtot = overall PM emission rate from all similar process
units, kg/Mg (lb/ton) of black liquor solids fired.ERPU1 = PM emission rate from process unit No. 1, kg/Mg (lb/
ton) of black liquor solids fired, calculated using Equation
2, 3, or 4 in paragraphs (a)(2)(i) through (iii) of this
section.PRPU1 = black liquor solids firing rate in Mg/d (ton/d) for
process unit No. 1, if process unit is a recovery furnace or
SDT. The CaO production rate in Mg/d (ton/d) for process unit
No. 1, if process unit is a lime kiln.PRtot = total black liquor solids firing rate in Mg/d (ton/d)
for all recovery furnaces in the chemical recovery system at
the kraft or soda pulp mill if the similar process units are
recovery furnaces or SDT, or the total CaO production rate in
Mg/d (ton/d) for all lime kilns in the chemical recovery
system at the mill if the similar process units are lime
kilns.ERPUi = PM emission rate from process unit No. i, kg/Mg (lb/
ton) of black liquor solids fired.PRPUi = black liquor solids firing rate in Mg/d (ton/d) for
process unit No. i, if process unit is a recovery furnace or
SDT. The CaO production rate in Mg/d (ton/d) for process unit
No. i, if process unit is a lime kiln.i=number of similar process units located in the chemical recovery
system at the kraft or soda pulp mill.
(v) The overall PM emission rate for the chemical recovery system at the mill must be determined using Equation 6 of this section as follows:[GRAPHIC] [TIFF OMITTED] TR12JA01.006 Where: ERtot = overall PM emission rate for the chemical recovery
system at the mill, kg/Mg (lb/ton) of black liquor solids
fired.ERRFtot = PM emission rate from all kraft or soda recovery
furnaces, calculated using Equation 2 or 5 in paragraphs
(a)(2)(i) and (iv) of this section, where applicable, kg/Mg
(2)(i) and (iv) of this section, where applicable, kg/Mg
(i) and (iv) of this section, where applicable, kg/Mg
(lb/ton) of black liquor solids fired.ERSDTtot = PM emission rate from all smelt dissolving tanks,
calculated using Equation 3 or 5 in paragraphs (a)(2)(ii) and
(iv) of this section, where applicable, kg/Mg (lb/ton) of
black liquor solids fired.ERLKtot = PM emission rate from all lime kilns, calculated
using Equation 4 or 5 in paragraphs (a)(2)(iii) and (iv) of
this section, where applicable, kg/Mg (lb/ton) of black liquor
solids fired.
(vi) After the Administrator has approved the PM emissions limits for each kraft or soda recovery furnace, smelt dissolving tank, and lime kiln, the owner or operator complying with an overall PM emission limit established in Sec. 63.862(a)(1)(ii) must demonstrate compliance with the HAP metals standard by demonstrating compliance with the approved PM emissions limits for each affected kraft or soda recovery furnace, smelt dissolving tank, and lime kiln, using the test methods and procedures in paragraph (b) of this section.
(b) The owner or operator seeking to determine compliance with Sec. 63.862(a), (b), or (d) must use the procedures in paragraphs (b)(1) through (6) of this section.
(1) For purposes of determining the concentration or mass of PM emitted from each kraft or soda recovery furnace, sulfite combustion unit, smelt dissolving tank, lime kiln, or the hog fuel dryer at Weyerhaeuser Paper Company's Cosmopolis, Washington facility (Emission Unit no. HD-14), Method 5 or 29 in appendix A of 40 CFR part 60 must be used, except that Method 17 in appendix A of 40 CFR part 60 may be used in lieu of Method 5 or Method 29 if a constant value of 0.009 g/dscm (0.004 gr/dscf) is added to the results of Method 17, and the stack temperature is no greater than 205 +C (400 +F). For Methods 5, 29, and 17, the sampling time and sample volume for each run must be at least 60 minutes and 0.90 dscm (31.8 dscf), and water must be used as the cleanup solvent instead of acetone in the sample recovery procedure.
(2) For sources complying with Sec. 63.862(a) or (b), the PM concentration must be corrected to the appropriate oxygen concentration using Equation 7 of this section as follows:[GRAPHIC] [TIFF OMITTED] TR18FE03.009 Where: Ccorr = The measured concentration corrected for oxygen, g/
dscm (gr/dscf);Cmeas = The measured concentration uncorrected for oxygen, g/
dscm (gr/dscf);X = The corrected volumetric oxygen concentration (8 percent for kraft
or soda recovery furnaces and sulfite combustion units and 10
percent for kraft or soda lime kilns); andY = The measured average volumetric oxygen concentration.
(3) Method 3A or 3B in appendix A of 40 CFR part 60 must be used to determine the oxygen concentration. The voluntary consensus standard ANSI/ASME PTC 19.10-1981--Part 10 (incorporated by reference--see Sec. 63.14) may be used as an alternative to using Method 3B. The gas sample must be taken at the same time and at the same traverse points as the particulate sample.
(4) For purposes of complying with of Sec. 63.862(a)(1)(ii)(A), the volumetric gas flow rate must be corrected to the appropriate oxygen concentration using Equation 8 of this section as follows: Qcorr = Qmeasx(21-Y)/(21-X) (Eq. 8) Where: Qcorr = the measured volumetric gas flow rate corrected for
oxygen, dscm/min (dscf/min).Qmeas = the measured volumetric gas flow rate uncorrected for
oxygen, dscm/min (dscf/min).Y=the measured average volumetric oxygen concentration.X=the corrected volumetric oxygen concentration (8 percent for kraft or
soda recovery furnaces and 10 percent for kraft or soda lime
kilns).
(5)(i) For purposes of selecting sampling port location and number of traverse points, Method 1 or 1A in appendix A of 40 CFR part 60 must be used;
(i) For purposes of selecting sampling port location and number of traverse points, Method 1 or 1A in appendix A of 40 CFR part 60 must be used;
(ii) For purposes of determining stack gas velocity and volumetric flow rate, Method 2, 2A, 2C, 2D, 2F, or 2G in appendix A of 40 CFR part 60 must be used;
(iii) For purposes of conducting gas analysis, Method 3, 3A, or 3B in appendix A of 40 CFR part 60 must be used. The voluntary consensus standard ANSI/ASME PTC 19.10-1981--Part 10 (incorporated by reference--see Sec. 63.14) may be used as an alternative to using Method 3B; and
(iv) For purposes of determining moisture content of stack gas, Method 4 in appendix A of 40 CFR part 60 must be used.
(6) Process data measured during the performance test must be used to determine the black liquor solids firing rate on a dry basis and the CaO production rate.
(c) The owner or operator of each affected source or process unit complying with the gaseous organic HAP standard in Sec. 63.862(c)(1) must demonstrate compliance according to the provisions in paragraphs (c)(1) and (2) of this section.
(1) The owner or operator complying through the use of an NDCE recovery furnace equipped with a dry ESP system is not required to conduct any performance testing to demonstrate compliance with the gaseous organic HAP standard.
(2) The owner or operator complying without using an NDCE recovery furnace equipped with a dry ESP system must use Method 308 in appendix A of this part, as well as the methods listed in paragraphs (b)(5)(i) through (iv) of this section. The sampling time and sample volume for each Method 308 run must be at least 60 minutes and 0.014 dscm (0.50 dscf), respectively.
(i) The emission rate from any new NDCE recovery furnace must be determined using Equation 9 of this section as follows:[GRAPHIC] [TIFF OMITTED] TR18FE03.010 Where: ERNDCE = Methanol emission rate from the NDCE recovery
furnace, kg/Mg (lb/ton) of black liquor solids fired;MRmeas = Measured methanol mass emission rate from the NDCE
recovery furnace, kg/hr (lb/hr); andBLS = Average black liquor solids firing rate of the NDCE recovery
furnace, megagrams per hour (Mg/hr) (tons per hour (ton/hr))
determined using process data measured during the performance
test.
(ii) The emission rate from any new DCE recovery furnace system must be determined using Equation 10 of this section as follows:[GRAPHIC] [TIFF OMITTED] TR18FE03.011 Where: ERDCE = Methanol emission rate from each DCE recovery furnace
system, kg/Mg (lb/ton) of black liquor solids fired;MRmeas,RF = Average measured methanol mass emission rate from
each DCE recovery furnace, kg/hr (lb/hr);MRmeas,BLO = Average measured methanol mass emission rate
from the black liquor oxidation system, kg/hr (lb/hr);BLSRF = Average black liquor solids firing rate for each DCE
recovery furnace, Mg/hr (ton/hr) determined using process data
measured during the performance test; and BLSBLO = The average mass rate of black liquor solids treated
in the black liquor oxidation system, Mg/hr (ton/hr)
determined using process data measured during the performance
test.
(d) The owner or operator seeking to determine compliance with the gaseous organic HAP standards in Sec. 63.862(c)(2) for semichemical combustion units must use Method 25A in appendix A of 40 CFR part 60, as well as the methods listed in paragraphs (b)(5)(i) through (iv) of this section. The sampling time for each Method 25A run must be at least 60 minutes. The calibration gas for each Method 25A run must be propane.
(1) The emission rate from any new or existing semichemical combustion unit must be determined using Equation 11 of this section as follows:[GRAPHIC] [TIFF OMITTED] TR18FE03.012 Where: ERSCCU = THC emission rate reported as carbon from each
semichemical combustion unit, kg/Mg (lb/ton) of black liquor
solids fired;THCmeas = Measured THC mass emission rate reported as carbon,
kg/hr (lb/hr); andBLS = Average black liquor solids firing rate, Mg/hr (ton/hr);
determined using process data measured during the performance
test.
(2) If the owner or operator of the semichemical combustion unit has selected the percentage reduction standards for THC, under Sec. 63.862(c)(2)(ii), the percentage reduction in THC emissions is computed using Equation 12 of this section as follows, provided that Ei and Eo are measured simultaneously:[GRAPHIC] [TIFF OMITTED] TR12JA01.012 Where: %RTHC = percentage reduction of total hydrocarbons emissions
achieved.Ei = measured THC mass emission rate at the THC control
device inlet, kg/hr (lb/hr).Eo = measured THC mass emission rate at the THC control
device outlet, kg/hr (lb/hr). [66 FR 3193, Jan. 12, 2001, as amended at 66 FR 37593, July 19, 2001; 68 FR 7716, Feb. 18, 2003; 68 FR 67955, Dec. 5, 2003]